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(L-446) 5-Member heterocyclic compound as diene: Diels–Alder reaction & 1,4-addition: with mechanism Video

#Furan, #furanasdiene, #heterocycliccompoundasdiene, #DielsAlderreaction, #cycloaddition, #pericyclicreaction,


In this lecture, I have discussed the diene character of five-member heterocyclic compounds (Furan, Pyrrole and Thiophene). I focused deeply on the role of aromaticity (stabilization energy) for the reactivity as well as selectivity. As a diene, I have discussed two main reactions like 1,4-addition reaction and Diels–Alder reaction. I have provided a mechanism for each step. Thanks for watching.

Links for some related videos are provided below. please visit them for better understanding ....

For "MCQ about Benzyne: For the exams like BS-MS, IIT-JEE, NEET, IIT-JAM, CSIR-NET, GATE, B.Sc, M.Sc etc." please click on the link "https://youtu.be/88iYrY7_k1U"

For "Preparation and stability of thio-acetal and thio-ketal: Complete mechanistic description." please click on the link "https://youtu.be/AcAHt652Pg0"

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For "Ipso Substitution: Electrophilic Aromatic Substitution (Part 3)." please click on the link "https://youtu.be/gZfc7uYxqL0"

For "Decarboxylation of five Heterocycles: Complete mechanistic description and role of Resonance energy." please click on the link "https://youtu.be/kUKenWhFhbA"

For "Aromatic electrophilic substitution on Five member heterocycles: Complete mechanistic description." please click on the link "https://youtu.be/EGnPC6cyJzY"

For "Pyrrole preparation from Muccic acid and Furan: Complete mechanistic description." please click on the link "https://youtu.be/XEN7EAq3KMk"

For "Preparation and Restrosynthetic of 1,4 dicarbonyl compounds: for five-member heterocycle preparation" please click on the link "https://youtu.be/XvVRcRzUf1A"

For "Diels–Alder reaction: Basic idea, importance & Examples with electron-donating & withdrawing groups." please click on the link "https://youtu.be/NBLcWHeIJtc"

For "L: 490: Endo vs Exo product in Diels Alder reaction: Molecular Orbital (MO) explanation of mechanism" please click on the link "https://youtu.be/0dqFJuudEGk"

For "MCQ-96: About Multi-step reaction of Furan: For BS-MS, CSIR-NET, GATE, IIT-JAM, B.Sc, M.Sc etc exams" please click on the link "https://youtu.be/zKuDqmIcl3g"

For "MCQ 108: About Selective epoxidation of diene (for BS-MS, CSIR-NET, IIT-JAM, B.Sc, IIT-JEE, NEET.)" please click on the link "https://youtu.be/yRMzRUe8xE0"

For "Protection and deprotection of C=C bond by Diels-Alder Reaction." please click on the link "https://youtu.be/OaEAuhmjxns"

For"3 types of Diene and reason for their difference by Dr. Tanmoy Biswas." please click on the link "https://youtu.be/JZq3Zy7l6T8"


For "(L-446) 5-Member heterocyclic compound as diene: Diels–Alder reaction & 1,4-addition: with mechanism" please click on the link "https://youtu.be/FMfZyDPCQfs"

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