Frustrated Lewis pair (FLP) or Frustrated Lewis-acid & Lewis-base pair catalyzed hydrogen activation Video
#FrustratedLewispair, #FLP, #FrustratedLewisacidbasepair, #hydrogenactivation, #FLPchemistry,
In this lecture, I have discussed the Frustrated Lewis pair (FLP) or Frustrated Lewis-acid & Lewis-base pair catalyzed hydrogen activation. This is a new topic in chemistry. This methodology results in metal-free activation of hydrogen and catalytic hydrogenation of organic functional groups like imine. This methodology is a unique design to get the heterolytic splitting of hydrogen molecules. I have also described the complete mechanism of this process. Additionally, I have discussed the preparation of one FLP in this video. I have also uploaded some videos related to this topic. Audiences are requested to watch them. The links are provided below.
For "Ammonia-Borane (NH3-BH3): Reducing agent and Future fuel (H2 storage) and CO2 reduction.." please click on the link "https://youtu.be/uRLmpU7OxqM"
For "Hydrogenation by of alkene by Transition Metals (mainly noble metals like Palladium or Platinum etc)" please click on the link "https://youtu.be/bXQEqhQTBkQ"
For "Cis-Decalin Vs. Trans-Decalin: A stability comparison with mechanism and application as H2 storage." please click on the link "https://youtu.be/ufBkLmpho94"
For "MCQ on borane and ethanol by Dr. Tanmoy Biswas (for IIT-JEE, NEET, BSMS, IIT-JAM, CSIR-NET, etc.)" please click on the link "https://youtu.be/DyO882IW0h4"
For "Video Lecture 5: Part III, Reactivity of Lithium Aluminium Hydride (LiAlH4)." please click on the link "https://youtu.be/09-51mFeJj8"
For "Video Lecture 5 (part II): Reactivity of borohydrides (MBH4) [mainly organic reactions]." please click on the link "Video Lecture: 5 (part I), Preparation, Bonding and Reactivity reactions) of borohydrides (MBH4)."
For "Question Answer discussion about Luche reaction (for CSIR-NET, GATE, JAM)" please click on the link "https://youtu.be/JEgL9tkqa1w"
For "Luche Reaction, selective reduction of ketone into secondary (2o) alcohol." please click on link "https://youtu.be/AA6S4eBqflY"
For "Wacker process for conversion of ethylene to acetaldehyde." please click on the link "https://youtu.be/pz08JhuAIxo"
For "Lindlar Catalyst, selective reduction of alkyne to cis-alkene." please click on the link "https://youtu.be/UQcWI8GAHzI".
For "Mesitoic acid (part 1) & contribution of both Steric & Electronic effect: Role of acylium cation." please click on the link "https://youtu.be/76QElDLaaf0"
For "Strategy for preparation of Mesitoic acid (part 2): Difficulties and its solution with the mechanism" please click on the link "https://youtu.be/Z7nB_bcMi7I"
For "Super Acid: Basic concept and Hammett Acidity Function." please click on the link "https://youtu.be/8H0QOLhybHM"
For "Super Base: Basic concept and different types." please click on the link "https://youtu.be/KRb9xlYEcQY"
For "Triflidic Acid: C-H bond as super acid." please click on "https://youtu.be/7583jOo4EWM"
For "Proton sponge: Basic concept and different types." please click on the link "https://youtu.be/J9Wr5mFcnxM"
For "Non-nucleophilic Base: Basic idea, Types (ionic and neutral) and Examples with Explanation." please click on the link "https://youtu.be/ZY3gRb4khKk"
For "Frustrated Lewis pair (FLP) or Frustrated Lewis-acid & Lewis-base pair catalyzed hydrogen activation" please click on the link "https://youtu.be/MGv74c8fljI"
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